Publications
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2010 Publications
- D. J. Lipomi, R. V. Martinez, R. M. Rioux, L. Cademartiri, W. F. Reus, G. M. Whitesides, Survey of Materials for Nanoskiving and Influence of the Cutting Process on the Nanostructures Produced, ACS Appl. Mater. Interf. 2 (2010) 2503.
- S. Elhadj, R. M. Rioux, M. D. Dickey, J. J. DeYoreo, G. M. Whitesides, Subnanometer Replica Molding of Molecular Steps on Ionic Crystals, Nano Lett. 10 (2010) 4140.
- S. H. Kim, F. H. Ribeiro, R. M. Rioux, Preface to the Molecular Surface Chemistry and its Applications Special Issue, Langmuir 26 (2010) 16187
- N. Chen, R. M. Rioux, L. A. M. M. Barbosa, F. H. Ribeiro, Kinetic and Theoretical Study of the Hydrodechlorination of CH4-xClx (x = 4) Compounds on Palladium, Langmuir 26 (2010) 16615
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2009 Publications
- J. Gingras, R. M. Rioux, D. Culvelier, N. A. Geisse, J. W. Lichtman, G. M. Whitesides, L. Mahadevan, J. R. Sanes, Controlling the orientation and synaptic differentiation of myotubes with micropatterned substrates. Biophys. J. 97 (2009) 2771.
- M. E. Grass, R. M. Rioux, G. A. Somorjai, Dependence of Gas-Phase Crotonaldehyde Hydrogenation Selectivity and Activity on the Size of Pt Nanoparticles (1.7-7.1 nm) Supported on SBA-15, Catal. Lett. 128 (2009) 1.
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2008 Publications
- Q. Xu, R. M. Rioux, M. D. Dickey, and G. M. Whitesides. Nanoskiving: A New Method to Produce Nanomaterials. Acc. Chem. Res. 41 (2008) 1566.
- R. M. Rioux, B. B. Hsu, H. Song, M. E. Grass, P. Yang and G. A. Somorjai. Influence of Pt particle size on selectivity in hydrocarbon conversion reactions: cyclohexene hydrogenation and dehydrogenation. Catal. Lett. 126 (2008) 10.
- D. A. Ruddy, J. Jarupatrakorn, R. M. Rioux, J. T. Miller, M. J. McMurdo, K. A. Tupper, and T. D. Tilley. Site-Isolated Pt-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pt(II) and Pt(IV). Chem. Mater. 20 (2008) 6517.
- M. E. Grass, Y. Yue, S. E. Habas, R. M. Rioux, C. I. Teall, P. Yang, and G. A. Somorjai. Silver ion controlled surface structures of platinum nanoparticles: Removal of Ag by selective etching leads to increased catalytic activity. J. Phys. Chem. C 112 (2008) 4797.
- R. M. Rioux, H. Song, M. Grass, J. D. Hoefelmeyer, K. Niesz, P. D. Yang, G. A. Somorjai. Kinetics and mechanism of the poisoning of ethylene hydrogenation by CO on silica-supported monodisperse Pt nanoparticles. J. Catal. 254 (2008) 1.
- R. M. Rioux, H. Song, M. Grass, J. D. Hoefelmeyer, K. Niesz, P. D. Yang, G. A. Somorjai. Adsorption and co-adsorption of ethylene and carbon monoxide on silica-supported monodisperse Pt nanoparticles. Volumetric and infrared spectroscopy studies. Langmuir 24 (2008) 198.
- T. J. Toops, W. N. Delgass, and R. M. Rioux, M. Albert Vannice Festschrift. Catal. Today 123 (2007) 2.
- Q. Xu, J. Bao, R. M. Rioux, R. Perez-Castejillos, F. Capasso, and G. M. Whitesides. Fabrication of Large-Area Patterned Nanostructures for Optical Applications by Nanoskiving. Nano Lett. 7 (2007) 2800. (Write-up in Photonics Spectra, November 2007).
- Q. Xu, R. M. Rioux, and G. M. Whitesides. Fabrication of Complex Nanostructures by Nanoskiving. ACS Nano 1 (2007) 215. Perspective in same issue (p. 151 by J. A. Rogers).
- R. M. Rioux, A. L. Marsh, J. S. Gaughan, and G. A. Somorjai. Oxidation and reforming reactions of methane on a stepped Pt(557) single crystal. Catal. Today 123 (2007) 265.
- R. M. Rioux, H. Song, S. Habas, M. Grass, K. Niesz, J. D. Hoefelmeyer, P. Yang, and G. A. Somorjai. Monodisperse Pt nanoparticles with well-defined surface structure: Synthesis, characterization, catalytic properties, and future prospects. Top. Catal. 39 (2006) 167.
- S. Kweskin, R. M. Rioux, S. E. Habas, K. Komvopoulos, P. Yang, and G. A. Somorjai. Carbon Monoxide Adsorption and Oxidation on Monolayer Films of Cubic Platinum Nanoparticles Investigated by Infrared-Visible Sum Frequency Generation Vibrational Spectroscopy. J. Phys. Chem. B, 110 (2006) 15920.
- G. A. Somorjai, A. M. Contreras, M. Montano, and R. M. Rioux. Clusters, Surfaces, and Catalysis. Proc. Natl. Acad., U. S. A. 103 (2006) 10577.
- H. Song, R. M. Rioux, R. Komor, J. D. Hoefelmeyer, K. Niesz, M. Grass, P. Yang, and G. A. Somorjai. Platinum nanoparticle encapsulation by hydrothermal synthesis of mesoporous SBA-15: Synthesis, characterization, and catalytic properties. J. Am. Chem. Soc. 128 (2006) 3027.
- M. Yang, R. M. Rioux, and G. A. Somorjai. Reaction kinetics and in-situ sum frequency generation surface vibrational spectroscopy studies of cycloalkene hydrogenation/ dehydrogenation on Pt(111): substituent effects and CO poisoning mechanism. J. Catal., 237 (2006) 255.
- R.M. Rioux and M. A. Vannice. Dehydrogenation of isopropyl alcohol on carbon-supported Pt and Cu-Pt catalysts. J. Catal. 233 (2005) 147. Corrigendum published in J. Catal. 234 (2005) 247.
- G. A. Somorjai and R. M. Rioux. High Technology Catalysts Towards 100% Selectivity. Fabrication, Characterization, and Reaction Studies. Catal. Today 100 (2005) 201.
- R. M. Rioux, H. Song, J. D. Hoefelmeyer, P. Yang, and G. A. Somorjai. High-Surface-Area Catalyst Design: Synthesis, Characterization, and Reaction Studies of Platinum Nanoparticles in Mesoporous SBA-15 Silica. J. Phys. Chem. B 109 (2005) 2192.
- N. Chen, R. M. Rioux, and F. H. Ribeiro. Hydrodechlorination reactions of 2-chloro-1,1,1,2-tetrafluoroethane and chloroethane in H2 and D2 on Pd catalysts. Appl. Catal. A-Gen. 271 (2004) 85.
- Y. Yin, R.M. Rioux, C. K. Erdonmez, S. Hughes, G. A. Somorjai, and A. P. Alivisatos. Formation of Hollow Nanocrystals through the Nanoscale Kirkendall Effect. Science 304 (2004) 711. (See Perspectives in same issue, J. M. Buriak, p. 692.)
- R. M. Rioux and M. A. Vannice. Hydrogenation/dehydrogenation: Isopropanol dehydrogenation over copper catalysts. J. Catal. 216 (2003) 362.
- N. Chen, R. M. Rioux, and F. H. Ribeiro. Investigation of Reaction Steps for the Hydrodechlorination of Chlorine-Containing Organic Compounds on Pd Catalysts. J. Catal. 211 (2002) 192.
- K. O. Nowack, R. M. Rioux, C. Na, X. Wu, and L. R. Radovic. A commentary on "Effect of metal additives on the physico-chemical characteristics of activated carbon exemplified by benzene and acetic acid adsorption." Carbon 39 (2001) 951.
- R. M. Rioux, C. D. Thompson, N. Chen, and F. H. Ribeiro. Hydrodechlorination of chlorofluorocarbons CF3-CFCl2 and CF3-CCl3 over Pd/C and Pd black catalysts. Catal. Today 62 (2000) 269.
- C. D. Thompson, R. M. Rioux, N. Chen, and F. H. Ribeiro. Turnover Rate, Reaction Order and Elementary Steps for the Hydrodechlorination of Chlorofluorocarbons on Palladium Catalysts. J. Phys. Chem. B 104 (2000) 3067.

